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توزیع شکلهای مختلف سرب، روی، کادمیم و مس در یک خاک آهکی آلوده | ||
دانش آب و خاک | ||
مقاله 5، دوره 30، شماره 4، دی 1399، صفحه 59-73 اصل مقاله (685.27 K) | ||
شناسه دیجیتال (DOI): 10.22034/ws.2020.11647 | ||
نویسندگان | ||
منوچهر قنبری یامچی1؛ شاهین اوستان* 2؛ عادل ریحانی تبار3 | ||
1دانشآموخته کارشناسی ارشد گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه تبریز | ||
2استاد گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه تبریز | ||
3دانشیار گروه علوم و مهندسی خاک، دانشکده کشاورزی، دانشگاه تبریز | ||
چکیده | ||
هدف از این پژوهش بررسی توزیع شکلهای شیمیایی سرب، روی، کادمیم و مس در دو غلظت و سه pH مختلف در یک خاک آهکی بود. سرب و روی در دو غلظت 1 و 10 میلیمول بر کیلوگرم و مس و کادمیم در دو غلظت 1/0 و 1 میلیمول برکیلوگرم از منبع نمک نیتراتی در سه سطح pH6، 7 و 8 به خاک افزوده شدند. نسبت خاک به محلول 1 به 20 در نظر گرفته شد. خاکها در دمای C° 1 ± 30 بهمدت 30 روز در انکوباتور نگهداری شدند. شکلهای شیمیایی فلزها در خاک به روش تسیر تعیین شد. نتایج نشان داد که pH بر توزیع شکلهای سرب و روی بومی خاک تأثیر نداشت. با افزایش pH از 6 به 8، شکل باقیمانده مس بومی کاهش یافته و شکل آلی آن افزایش یافت. با توجه به حد تعیین مقدار (LOQ) دستگاه جذب اتمی، کادمیم بومی خاک قابل اندازهگیری نبود. تأثیر pH بر توزیع فلزها بین شکلهای مختلف بسته به نوع فلز و غلظت آن متفاوت بود. شکلهای اکسیدی و آلی در غلظت کم سرب و شکلهای اکسیدی و کربناتی در غلظت زیاد این فلز غالب بودند. همچنین، روی و مس افزوده شده بهترتیب بیشتر به شکلهای اکسیدی و آلی تجمع یافتند. کادمیم افزوده شده در غلظت کم به شکل آلی و در غلظت زیاد به شکل تبادلی تجمع یافت. نتایج نشان داد که با 10 برابر شدن غلظت اولیه فلزها، فاکتور تحرک فلزها بهطور متوسط 8/1 برابر افزایش یافت. فاکتور تحرک فلزها با افزایش pH تغییر قابلملاحظهای نکرد. | ||
کلیدواژهها | ||
روش تسیر؛ خاک آهکی؛ شکل بومی فلز؛ فاکتور تحرک؛ pH | ||
مراجع | ||
Agbenin JO, 2010. Extractability and transformation of copper and zinc added to tropical savanna soil under long-term pasture. Commun Soil Sci Plant Anal 41(8): 1016-1027. Ahnstrom ZS and Parker, D.R.1999. Development and assessment of a sequential extraction procedure for the fractionation of soil cadmium. Soil Sci Soc Amer J 63: 1650-1658. Ahumada I, Escudero P, Adriana Carrasco M, Castillo G, Ascra L and Fuentes E, 2004.Use of sequential extraction to assess the influence of sewage sludge amendment on metal mobility in Chilean soils. J Environ Monit 6(4): 327-334. Akbar K, Hale W, Headly A and Athar M, 2006. Heavy metal contamination of roadside soils of northern England. Soil Water Res 1(4): 158-163. Allison LE and Moodie CD, 1965.Carbonates. Pp.1379-1396. In: Black CA (ed), Methods of Soil Analysis. Part 2: Chemical and microbiological properties. American Society of Agronomy, Madison, WI. Alva AK, Huang B and Paramasivam S, 2001. Soil pH Affects Copper Fractionation and Phytotoxicity. Soil Sci Soc Amer J 64: 3: 955-962. Anonymous, 2007. Flame atomic absorption spectrophotometry. Method 7000B. United States Environmental Protection Agency, Washington, D.C., USA. https://www.epa.gov/sites/production/files/2015-12/documents/7000b.pdf. Arenas-Lago D, Vegaa FA, Silva LFO and Andrade ML, 2013. Soil interaction and fractionation of added cadmium in some Galician soils. Microchem J 110: 681-690. Appel CH and Ma L, 2002. Concentration, pH, and surface charge effects on cadmium and lead sorption in three tropical soils. J Environ Qual 31: 581-589. Atkinson NR, Bailey EH, Tye AM, Breward N and Young SD, 2011. Fractionation of lead in soil by isotopic dilution and sequential extraction. Environ Chem 8: 493–500. Baghaie AH, Khoshgoftarmanesh AH, Afyuni M, 2012.Effects of Inorganic and Organic Fractions of Enriched Cow Manure and Sewage Sludge on Distribution of Lead Chemical Fractionation in Soil. JWSS 16(60): 95-106. Bakirdere S and Yaman M, 2008. Determination of lead, cadmium and copper in roadside soil and plants in Elazig, Turkey. Environ Monit Assess 136(1-3): 401-410. Behera SK and Shukla AK, 2013. Depth-wise distribution of zinc, copper, manganese and iron in acid soils of India and their relationship with some soil properties. J Indian Soc Soil Sci. 61(3): 244-252. Benfenati E, Valzacchi S, Mariani G, Airoldi L and Fanelli R, 1992. PCDD, PCDF, PCB, PAH, cadmium and lead in roadside soil: relationship between road distance and concentration. Chemosphere 24(8): 1077-1083. Bingham FT, Page AL, Mahler RJ and Ganje TJ, 1975. Cadmium availability to rice in sludge-amended soil under “flood” and “nonflood” culture. Soil Sci Soc Amer J 40(5): 715-719. Boekhold AE, Temminghoff EJM and Van der Zee SEATM, 1993. Influence of electrolyte composition and pH on cadmium sorption by an acid sandy soil. J Soil Sci 44: 85–96. Brown S, Chaney R and Angle JS, 1997. Subsurface liming and metal movement in soils amended with lime-stabilized biosolids. J Environ Qual 26: 724-732. Chlopecka A, Bacon, JP, Wilson MJ and Kay J, 1996. Forms of cadmium, lead, and zinc in contaminated soils from Southwestern Poland. J Environ Qual 25: 69-79. Chapman HD, 1965. Cation exchange capacity. Pp.114-117. In: Black CA (ed), Methods of Soil Analysis. Part 2: Chemical and microbiological properties. American Society of Agronomy, Madison, WI. Chen M and Ma LQ, 2001. Comparison of three aqua regia digestion methods for twenty Florida soils. Soil Sci Soc Am J 65: 491–499. Dennis EJ, 1971. Micronutrients: A New Dimension in Agriculture the National Fertilizer Solutions Association (NFSA), Illinois, USA. Farrah H and Pickering WF, 1977. Influence of clay-solute interactions on aqueous heavy metal ion levels. Water Air Soil Pollut , 8: 189–197. Fedotov PS, Zavarzina AG, Spivakov BY, Wennrich R, Mattusch J, Titze Kde P and Demin, V, 2002. Accelerated fractionation of heavy metals in contaminated soils and sediments using rotating coiled columns. J Environ Monit 4: 318-324. Gee GW and Bauder JW, 1986. Particle-size analysis. Pp. 383-411. In: Klute A (ed), Methods of Soil Analysis. Part 1: Physical methods. American Society of Agronomy, Madison, WI. Geiger G, Schulin R, Furrer G, 1994. Effects of changing environmental conditions on the binding capacity of soil organic matter for heavy metals. “CTB Project”, Hoofddorp, The Netherlands. Reprint by Institute of Terrestrial Ecology, ETH Zurich. Greger M, 2004. Metal availability, uptake, transport and accumulation in plants. Pp.1-27. In: Prasad MNV (ed), Heavy Metal Stress in Plants: From Biomolecules to Ecosystems. Second edition. Springer. Gungor EBO and Orkun MO, 2014. Fractionation, mobility, and sources of selected heavy metals in topsoils from the middle black sea region of Turkey. Clean-Soil Air Water 42(7): 986-993. Gunkel P, Jezequel K, and Faber B, 2002.Temporal evolution of copper distribution in soil fractions influence of soil pH and organic carbon level on copper distribution. Environ Technol 23(9): 1001-1008. Han FX, Kingery WL and Selim HM, 2001. Accumulation, redistribution, transport, and bioavailability of heavy metals in waste-amended soils. Pp.145-174. In: Iskandar IK and Kirkham MB (eds), Trace Elements in Soil, Bioavailability, Flux and Transfer. Lewis Publishers, Boca Raton, Florida, USA. Inaba S and Takenaka C, 2005. Changes in chemical species of copper added to Brown forest soil in Japan. Water Air Soil Pollut 162: 285–293. Lei M, Zhang Y, Khan S, Qin PF, Liao BH, 2010. Pollution, fractionation, and mobility of Pb, Cd, Cu, and Zn in garden and paddy soils from a Pb/Zn mining area. Environ Monit Assess 168(1-4): 22-215. Harrison RM, 1981. Chemical association of lead, Cd, Cu, and Zn in street dusts and roadside soils. Environ Sci Technol 15: 1378- 1383. Iyengar SS, Martens DC and Miller WP, 1981. Distribution and plant availability of soil zinc fractions. Soil Sci Soc Amer J 45: 735-739. Lianga S, Guan D-X, Ren J-H, Zhang M, Luo J and Ma LQ, 2014. Effect of aging on arsenic and lead fractionation and availability in soils: Coupling sequential extractions with diffusive gradients in thin-films technique .J Hazard Mater 273: 272–279. Ma LQ and Rao GN, 1997.Chemical fractionation of cadmium, copper, nickel and zinc in contaminated soils. J Environ Qual 26: 259-264. Ma YB and Uren N, 1997.The fate and transformations of zinc added to soils. Aust J Soil Res 35(4): 727 – 738. McKenzie RM, 1980. Adsorption of lead and other heavy metals on oxides of manganese and iron. Aust J Soil Res 18(1): 61-73 27. McLean EO, 1982. Soil pH and lime requirement. Pp.199-224. In: Page AL (ed), Methods of Soil Analysis. Part 2: Chemical and microbiological properties. America Society of Agronomy, Madison, WI. Lei M, Liao B-H, Zeng Q-R, Qing P-F, and Khan S, 2008. Fraction distributions of lead, cadmium, copper and zinc in metal contaminated soil before and after extraction with disodium ethylenediaminetetraacetic acid. Commun Soil Sci Plant Anal 39: 1963-1978. Morera MT, Echeverria JC, Mazkiaran C, Garrido JJ, 2001. Isotherm and sequential extraction procedures for evaluating sorption and distribution of heavy metals in soils. Environ Pollut 113: 135-144. Nyamangara J, 1998. Use of sequential extraction to evaluate zinc and copper in a soil amended with sewage sludge and inorganic metal salts. Agric Ecosyst Environ 69: 135–141. Nelson DW and Sommers LE, 1982. Total carbon, organic carbon and organic matter. Pp. 539-579. In: Page AL (ed). Method of Soil Analysis. Part 2. American Society of Agronomy, Madison, WI. Norrstrom AC and Jacks G, 1998. Concentration and fractionation of heavy metals in roadside soils receiving de-icing salts. Sci Tot Environ 218: 161-174. Ogundiran MB and Osibanjo O, 2009. Mobility and speciation of heavy metals in soils impacted by hazardous waste. Chem Spec Bioavailab 21(2): 59-69. Othman I, Al-Oudat M and Al-Masri MS, 1997. Lead levels in roadside soils and vegetation of Damascus city. Sci Tot Environ 207(1): 43-48. Piotrowska M and Dudka S, 1994. Estimation of maximum permissible levels of cadmium in a light soil by using cereal plants. Water Air Soil Pollut 73(1): 179–188. Parizanganeh A, Hajisoltani P and Zamani A, 2010. Assessment of heavy metal pollution in surficial soils surrounding Zinc Industrial Complex in Zanjan-Iran. Procedia Environmental Sciences 2: 162-166. Planquarta P, Boninb G, Pronea A and Massiania C, 1999. Distribution, movement and plant availability of trace metals in soils amended with sewage sludge composts: application to low metal loadings. Sci Tot Environ 241(1–3): 161-179. Reddy NC and Patrick Jr. WH, 1977. Effect of redox potential and pH on the uptake of cadmium and lead by rice plants. J Environ Qual 6(3): 259-262. Rengle Z, 2002. Hand Book of Plant Growth: pH as the master variable. Marcel Dekker, Inc. New York, Basel. Reyhanitabar A, Karimian N, Ardalan M, Savaghebi GR and Ghanadha MR, 2006. Distribution of different forms of Zn and its relation with soil properties in some calcareous soils of Tehran province. JAST 3: 125-135. Rhoades, J.D. 1996. Salinity: Electrical conductivity and total dissolved solids. Pp. 417-435. In: Sparks DL (ed). Methods of Soil Analysis. Part 3: Chemical methods. Soil Sci Soc Am. Madison, WI. Rieuwerts JS, Thornton I, Farago ME and Ashmore MR, 1998. Factors influencing metal bioavailability in soils: preliminary investigations for the development of a critical loads approach for metals. Chem Spec Bioavailab 10 (2): 61-75. Segarra MJB, Prego R, Wilson MJ, Bacon J and Santos-Echeandia JS, 2008. Metal speciation in surface sediments of the Vigo Ria. Scientia Marina 72(1): 119-126. Shober AL, Stehouwer RC and MacNeal KE, 2007. Chemical fractionation of trace elements in biosolid-amended soils and correlation with trace elements in crop tissue. Commun Soil Sci Plant Anal 38(7-8): 1029-1046. Shuman LM, 1988. Effect of organic matter on the distribution of manganese, copper, iron and zinc in soil fraction. Soil Sci 146: 192-198. Sipos P, 2009.Distribution and sorption of potentially toxic metals in four forest soils from Hungary. CEJG 1(2): 183 -192. Sposito G, Lund LJ, Chang AC, 1982. Trace metal chemistry in arid-zone field soils amended with sewage sludge: I. Fractionation of Ni, Cu, Zn, Cd and Pd in solid phases. Soil Sci Soc Amer J 46: 260-264. Stumm W and Morgan JJ, 1981. Aquatic Chemistry: An introduction emphasizing chemical equilibria in natural waters. 2nd ed. John Wiley & Sons, New York. Svendson A, Henry C, Brown S, 2007. Revegetation of high zinc and lead tailings with municipal biosolids and lime: greenhouse study. J Environ Qual. 36: 1609–1617. Tessier A, Campbell PGC and Bisson M, 1979. Sequential Extraction procedure for the speciation of particular trace metals. Anal Chem 51: 1-22. Tsadilas CD, 2001. Soil pH effect on the distribution of heavy metals among soil fractions. Pp.107-120. In: Iskandar IK (ed), Environmental Restoration of Metals-Contaminated Soils. Lewis Publishers, Boca Raton. Uzoho BU, Nkwopara UN, Ihem E, Eke C, Odum JC and Onwudike S, 2014. Chemical speciation and mobility of cadmium and lead in waste dumpsites in Owerri, Southeastern Nigeria. JCBPSC 4(2): 1721-1734. Vanek A, Boruvka L, Drabek O, Mihaljevic M, Komarek M, 2005. Mobility of lead, zinc and cadmium in alluvial soils heavily polluted by smelting industry. Plant Soil Environ 51(7): 316–321. Voegelin A, Tokpa G, Jacquat O, Barmettler K and Kretzschmar R, 2008. Zinc fractionation in contaminated soils sequential and single extractions: influence of soil properties and zinc content. J Environ Qual 37: 1190-1200. Wang Y and Chen M, 2011.Variation of the fraction transformations and mobility of Cu and Zn in municipal sludge with pH. Second International Conference on Mechanic Automation and Control Engineering (MACE), 15-17 July, Inner Mongolia, China. Wang WS, Shan XQ, Wen B and Zhang SZ, 2003. Relationship between the extractable metals from soils and metals taken up by maize roots and shoots. Chemosphere 53: 523–530. WHO, 1996. Permissible Limits of Heavy Metals in Soil and Plants. World Health Organization, Geneva Switzerland. Xiang HF, Tang HA, Ying QH, 1995. Transformation and distribution of forms of zinc in acid, neutral and calcareous soils of China. Geoderma 66: 121–135. Xiong L-M and Lu R-K, 1993. Effect of liming on plant accumulation of cadmium under upland or flooded conditions. Environ Pollut 79: 199–203. Yang HF, Wang YB and Huang YJ, 2015. Chemical fractions and phytoavailability of copper to rape grown in the polluted paddy soil. Int J Environ Sci Technol 12: 2929–2938. Yu Y and Zhou QX, 2006. Impacts of soybean growth on Cu speciation and distribution in two rhizosphere soils. Biol Fert Soils 42(5): 450-456. Yusuf KA, 2007. Sequential extraction of lead, copper, cadmium and zinc in soils near Ojota waste site. J Agron 6(2): 331-337.
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